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Консультация № 110007
18.11.2007, 16:50
0.00 руб.
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1
1
Электролиз.
Анод: Ag
Катод: Cu
Состав электролита: AgNO3
водный раствор.
Условие: Воздух.
Анод: Ag
Катод: Cu
Состав электролита: AgNO3
водный раствор.
Условие: Воздух.
Обсуждение
Неизвестный
18.11.2007, 16:57
общий
это ответ
Здравствуйте, Зайцев Александр Сергеевич!
Если Вы уверены, что столь коротко записанное условие является правильным, то вот Вам ответ:
Если Cu - катод, то на нем будет происходить восстановление атмосферного кислорода, входящего в состав воздуха. Реакция будет происходить такая:
O<sub>2</sub> + 2H<sub>2</sub>O + 4e = 4OH<sup>-</sup>
На аноде будет идти окисление серебра.
Ag - e = Ag<sup>+</sup>
Суммарный процесс:
4Ag + O<sub>2</sub> + 2H<sub>2</sub>O = 4AgOH.
Еще раз обращаю внимание, серебро стоит правее меди в ряду напряжений, поэтому описанная в задаче ситуация для него является нетипичной(типичная ситуация - все с точностью до наоборот)! Не говорите потом, что я не предупредил. Удачи!
Если Вы уверены, что столь коротко записанное условие является правильным, то вот Вам ответ:
Если Cu - катод, то на нем будет происходить восстановление атмосферного кислорода, входящего в состав воздуха. Реакция будет происходить такая:
O<sub>2</sub> + 2H<sub>2</sub>O + 4e = 4OH<sup>-</sup>
На аноде будет идти окисление серебра.
Ag - e = Ag<sup>+</sup>
Суммарный процесс:
4Ag + O<sub>2</sub> + 2H<sub>2</sub>O = 4AgOH.
Еще раз обращаю внимание, серебро стоит правее меди в ряду напряжений, поэтому описанная в задаче ситуация для него является нетипичной(типичная ситуация - все с точностью до наоборот)! Не говорите потом, что я не предупредил. Удачи!
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