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Консультация № 110000
18.11.2007, 16:08
0.00 руб.
0
2
2
Здравствуйте! Помогите мне, пожалуйста, решить такую задачку:
рассчитать энергию Гиббса химической реакции синтеза аммиака 1/2N2+3/2H2=NH3 при 298 К.
Спасибо!
рассчитать энергию Гиббса химической реакции синтеза аммиака 1/2N2+3/2H2=NH3 при 298 К.
Спасибо!
Обсуждение
Неизвестный
18.11.2007, 16:24
общий
это ответ
Здравствуйте, Нуруллина Венера Равилевна!
Находим энергии Гиббса образования для каждого из веществ:
dG(N<sub>2</sub>) = 0
dG(H<sub>2</sub>) = 0
dG(NH<sub>3</sub>) = -16.66 кДж/моль.
dG<sub>r</sub> = dG(NH<sub>3</sub>) - 1/2 * dG(N<sub>2</sub>) - 3/2 * dG(H<sub>2</sub>) = -16.66 кДж.
Ответ: -16.66 кДж.
Находим энергии Гиббса образования для каждого из веществ:
dG(N<sub>2</sub>) = 0
dG(H<sub>2</sub>) = 0
dG(NH<sub>3</sub>) = -16.66 кДж/моль.
dG<sub>r</sub> = dG(NH<sub>3</sub>) - 1/2 * dG(N<sub>2</sub>) - 3/2 * dG(H<sub>2</sub>) = -16.66 кДж.
Ответ: -16.66 кДж.
Неизвестный
18.11.2007, 17:01
общий
это ответ
Здравствуйте, Нуруллина Венера Равилевна!
Можно рассчитать энергию Гиббса исходя из энтальпий и энтропий
dH(N2)г=0
dH(H2)г=0
dH(NH3)г=-46,19 кДж/моль
S(N2)г=199,9 Дж/моль/К
S(H2)гг=130,52 Дж/моль/К
S(NH3)г=192,6 Дж/моль/К
dS реакции= 1моль*192,6 Дж/моль/К -1/2 моль* 199,9 Дж/моль/К -3/2моль*130,52 Дж/моль/К =-103,13Дж/К
dH=-46.19 кДж
dG=-46190Дж -298К *(-101,13Дж/К)=-16,053кДж
Можно рассчитать энергию Гиббса исходя из энтальпий и энтропий
dH(N2)г=0
dH(H2)г=0
dH(NH3)г=-46,19 кДж/моль
S(N2)г=199,9 Дж/моль/К
S(H2)гг=130,52 Дж/моль/К
S(NH3)г=192,6 Дж/моль/К
dS реакции= 1моль*192,6 Дж/моль/К -1/2 моль* 199,9 Дж/моль/К -3/2моль*130,52 Дж/моль/К =-103,13Дж/К
dH=-46.19 кДж
dG=-46190Дж -298К *(-101,13Дж/К)=-16,053кДж
Форма ответа
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