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Консультация № 109949
18.11.2007, 09:43
0.00 руб.
0
1
1
Зравствуйте! Вот такая задача:
Э.д.с. гальванического элемента, образованного никелем, погруженным в раствор его соли с концентрацией ионов Ni<sup>2+</sup> 10<sup>–4</sup> моль/л, и серебром, погруженным в раствор его соли, равна 1,108 В. Определите концентрацию ионов Ag<sup>+</sup> в растворе его соли. Составьте схему работы данного ГЭ.
Буду благодарен за решение.
Э.д.с. гальванического элемента, образованного никелем, погруженным в раствор его соли с концентрацией ионов Ni<sup>2+</sup> 10<sup>–4</sup> моль/л, и серебром, погруженным в раствор его соли, равна 1,108 В. Определите концентрацию ионов Ag<sup>+</sup> в растворе его соли. Составьте схему работы данного ГЭ.
Буду благодарен за решение.
Обсуждение
Неизвестный
18.11.2007, 11:20
общий
это ответ
Здравствуйте, piit!
E=Eоксил - E восст
Еокисл=E(Ag(+)/Ag)=E0+0,059/1*lg(C(Ag(+))) где 1 это число отданных электронов в следующей полуреакции Ag=Ag(+) + 1 e
Евосст=E(Ni(2+)/Ni)=E0+0,059/2*lg(C(Ni(2+)))
Eвосст=-0,250В + 0,059В/2*lg(10^-4)=-0.250В-4/2*0,059В=-0,368В
Е окисл = 1,108В + (-0,368В) =0,740В
lg(C(Ag(+)))=(0,740В-0,799В{стандартный электродный потенциал})/0,059=-1
C(Ag(+))=10^-1=0.1 моль/л
Ag | Ag(+) || Ni(2+) | Ni
Ag(+) + 1e=Ag
Ni - 2e =Ni(2+)
E=Eоксил - E восст
Еокисл=E(Ag(+)/Ag)=E0+0,059/1*lg(C(Ag(+))) где 1 это число отданных электронов в следующей полуреакции Ag=Ag(+) + 1 e
Евосст=E(Ni(2+)/Ni)=E0+0,059/2*lg(C(Ni(2+)))
Eвосст=-0,250В + 0,059В/2*lg(10^-4)=-0.250В-4/2*0,059В=-0,368В
Е окисл = 1,108В + (-0,368В) =0,740В
lg(C(Ag(+)))=(0,740В-0,799В{стандартный электродный потенциал})/0,059=-1
C(Ag(+))=10^-1=0.1 моль/л
Ag | Ag(+) || Ni(2+) | Ni
Ag(+) + 1e=Ag
Ni - 2e =Ni(2+)
Форма ответа
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