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Консультация № 199540
06.11.2020, 18:15
0.00 руб.
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Здравствуйте, уважаемые эксперты! Прошу вас ответить на следующий вопрос: В герметичном сосуде находятся 1 моль неона и 2 моля водорода H2. При температуре T1=300 К, когда весь водород находится в молекулярном состоянии, давление в сосуде p1=10^5 Па. При нагревании содержимого сосуда до температуры T2=3000 К давление возросло до p_2=1,5*10^6 Па. Какая часть молекул водорода диссоциировала (распалась) на атомы?
Обсуждение
11.11.2020, 17:22
общий
это ответ
Здравствуйте, Nekro!
Для [$957$] молей газа связь его давления P, объёма V и температуры T описывается уравнением Менделеева-Клайперона:
Так как сосуд герметичен, то V = const и
откуда
Подставляя исходные данные (T[sub]1[/sub] = 300 K, P[sub]1[/sub] = 100000 Па, T[sub]2[/sub] = 3000 K, P[sub]2[/sub] = 1500000 Па, [$957$][sub]1[/sub] = 1 + 2 = 3 моль), получаем
моль.
Из них 1 моль по-прежнему приходится на неон (он не диссоциировал), остальные 3.5 моля - на водород, в том числе 0.5 моля, оставшиеся в молекулярном состоянии, и 1.5 моля, превратившихся при диссоциации в 3 моля (2[$183$]1.5) атомарного водорода. Таким образом, диссоциировало 75% водорода.
Для [$957$] молей газа связь его давления P, объёма V и температуры T описывается уравнением Менделеева-Клайперона:
Так как сосуд герметичен, то V = const и
откуда
Подставляя исходные данные (T[sub]1[/sub] = 300 K, P[sub]1[/sub] = 100000 Па, T[sub]2[/sub] = 3000 K, P[sub]2[/sub] = 1500000 Па, [$957$][sub]1[/sub] = 1 + 2 = 3 моль), получаем
моль.Из них 1 моль по-прежнему приходится на неон (он не диссоциировал), остальные 3.5 моля - на водород, в том числе 0.5 моля, оставшиеся в молекулярном состоянии, и 1.5 моля, превратившихся при диссоциации в 3 моля (2[$183$]1.5) атомарного водорода. Таким образом, диссоциировало 75% водорода.
5
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