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Консультация № 180652
Обсуждение
09.11.2010, 21:46
общий
это ответ
Здравствуйте, Козловский Константин Викторович!
значения, принимаемые квантовыми числами:
n - определяет электронный уровень, принимает натуральные значения 1, 2, 3 ...
l - определяет форму орбитали (l=0 - s, l=1 - p, l=2 - d, l=3 - f), принимает целые значения от 0 до n-1 (0[$8804$]l[$8804$]n-1)
Поэтому невозможен 3f-подуровень (n=3, l=3), невозможна и конфигурация 3f5
m[sub]l[/sub] - определяет расположение орбитали. Принимает целые значения -l[$8804$]ml[$8804$]l
количество возможных значений ml (2l+1) определяет количество орбиталей подуровня
m[sub]s[/sub] - спин принимает 2 значения +1/2 и -1/2
Таким образом, для подуровня возможны 4l+2 сочетаний магнитного и спинового квантовых чисел. Согласно принципу Паули 2 электрона не могут иметь идентичный набор квантовых чисел, следовательно подуровень не может содержать более чем 4l+2 электрона. (для s-подуровня 2 электрона, для p - 6, для d - 10, для f -14)
Этот принцип нарушают следующие невозможные конфигурации:
2p7 (l=1; максимальное число электронов 4l+2=6)
3s3 (l=0; максимальное число электронов 4l+2=2)
значения, принимаемые квантовыми числами:
n - определяет электронный уровень, принимает натуральные значения 1, 2, 3 ...
l - определяет форму орбитали (l=0 - s, l=1 - p, l=2 - d, l=3 - f), принимает целые значения от 0 до n-1 (0[$8804$]l[$8804$]n-1)
Поэтому невозможен 3f-подуровень (n=3, l=3), невозможна и конфигурация 3f5
m[sub]l[/sub] - определяет расположение орбитали. Принимает целые значения -l[$8804$]ml[$8804$]l
количество возможных значений ml (2l+1) определяет количество орбиталей подуровня
m[sub]s[/sub] - спин принимает 2 значения +1/2 и -1/2
Таким образом, для подуровня возможны 4l+2 сочетаний магнитного и спинового квантовых чисел. Согласно принципу Паули 2 электрона не могут иметь идентичный набор квантовых чисел, следовательно подуровень не может содержать более чем 4l+2 электрона. (для s-подуровня 2 электрона, для p - 6, для d - 10, для f -14)
Этот принцип нарушают следующие невозможные конфигурации:
2p7 (l=1; максимальное число электронов 4l+2=6)
3s3 (l=0; максимальное число электронов 4l+2=2)
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