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Консультация № 178122
30.04.2010, 14:37
35.95 руб.
0
1
1
Доброго времени суток, уважаемые эксперты!
Прошу вашей помощи в решении следующей задачи.
Задача.
Составьте координационные формулы следующих соединений серебра: AgCl[$149$]2NH[sub]3[/sub], AgCN[$149$]KCN. Координационное число серебра равно двум. Напишите уравнения диссоциации этих соединений в водном растворе и выражения для К[sub]нест[/sub].
Заранее спасибо.
Прошу вашей помощи в решении следующей задачи.
Задача.
Составьте координационные формулы следующих соединений серебра: AgCl[$149$]2NH[sub]3[/sub], AgCN[$149$]KCN. Координационное число серебра равно двум. Напишите уравнения диссоциации этих соединений в водном растворе и выражения для К[sub]нест[/sub].
Заранее спасибо.
Обсуждение
Неизвестный
30.04.2010, 16:03
общий
это ответ
Здравствуйте, Botsman.
AgCl•2NH3 - [Ag (NH3)2]Cl хлорид диаминсеребра в водном растворе диссоциирует [Ag (NH3)2]Cl =[Ag (NH3)2]+ + Cl-
Комплексный ион диссоциирует [Ag (NH3)2]+ = Ag+ + 2 NH3
Константа нестойкости имеет вид Кнест = [ Ag+] [$149$][ NH3]2/[Ag (NH3)2]
AgCN •KCN – K[Ag(CN)2] дицианоаргентат калия в водном растворе диссоциирует K[Ag(CN)2] = K+ + [Ag(CN)2]-
Комплексный ион диссоциирует [Ag(CN)2]- = Ag+ + 2 CN-
Константа нестойкости Кнест = [ Ag+] *[ CN-]2/[Ag (CN-)2]
AgCl•2NH3 - [Ag (NH3)2]Cl хлорид диаминсеребра в водном растворе диссоциирует [Ag (NH3)2]Cl =[Ag (NH3)2]+ + Cl-
Комплексный ион диссоциирует [Ag (NH3)2]+ = Ag+ + 2 NH3
Константа нестойкости имеет вид Кнест = [ Ag+] [$149$][ NH3]2/[Ag (NH3)2]
AgCN •KCN – K[Ag(CN)2] дицианоаргентат калия в водном растворе диссоциирует K[Ag(CN)2] = K+ + [Ag(CN)2]-
Комплексный ион диссоциирует [Ag(CN)2]- = Ag+ + 2 CN-
Константа нестойкости Кнест = [ Ag+] *[ CN-]2/[Ag (CN-)2]
5
Спасибо!
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