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Консультация № 176797
20.02.2010, 15:46
43.65 руб.
0
3
1
Здравствуйте! Помогите пожалуйста с задачами. Зарание спасибо. 1)Выразите молекулярными и ионными уравнениями следующие реакции, объясните возможность или невозможность протекания этих реакций(используя Кн и ПР осадков): Fe2(SO4)3→[Fe(CNS)6]³ˉ→[FeF6]³ˉ →[Fe(CN)6]³ˉ→Fe(OH)3
2)Рассчитайте молярную концентрацию эквивалента H2S ,если при взаимодействии 150мл его водного раствора с бромной водой образуется 0,95г осадка.Какой объем 0,25н раствора NaOH можно нейтролизовать исходным раствором сероводорода?
2)Рассчитайте молярную концентрацию эквивалента H2S ,если при взаимодействии 150мл его водного раствора с бромной водой образуется 0,95г осадка.Какой объем 0,25н раствора NaOH можно нейтролизовать исходным раствором сероводорода?
Обсуждение
Неизвестный
21.02.2010, 14:33
общий
это ответ
Здравствуйте, oksan-ka.
H2S + Br2 = 2HBr + S
=> осадок - S
найдем количество вещества S = 0.95г/32(г/моль)=0,02969моль
количество вещества сероводорода по уравнению реакции также равно 0,02969моль
0,02969моль H2S содержится в 150мл=0.15л
Тогда См = 0,02969моль/0.15л = 0,1979моль/л
теперь напишем реакцию с NaOH
H2S+2NaOH=Na2S+2H2O
по уравнению реакции на 1 моль H2S реагирует 2 моль NaOH
Количество вещества NaOH = 2*0,02969моль=0.05938моль
Объем раствора NaOH V=0.05938моль/(0,25моль/л)=0.238л
H2S + Br2 = 2HBr + S
=> осадок - S
найдем количество вещества S = 0.95г/32(г/моль)=0,02969моль
количество вещества сероводорода по уравнению реакции также равно 0,02969моль
0,02969моль H2S содержится в 150мл=0.15л
Тогда См = 0,02969моль/0.15л = 0,1979моль/л
теперь напишем реакцию с NaOH
H2S+2NaOH=Na2S+2H2O
по уравнению реакции на 1 моль H2S реагирует 2 моль NaOH
Количество вещества NaOH = 2*0,02969моль=0.05938моль
Объем раствора NaOH V=0.05938моль/(0,25моль/л)=0.238л
Форма ответа
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