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Консультация № 182483
12.03.2011, 09:50
58.03 руб.
0
1
1
Здравствуйте! У меня возникли сложности с таким вопросом:
Реакции выражаются схемами:
KClO3 + H2SO4 + FeSO4 → KCl + H2O + Fe2(SO4)3
Zn + HNO3 → Zn(NO3)2 + H2O + N2O
Составьте электронные уравнения. Расставьте коэффициенты в уравнениях реакций. Для каждой реакции укажите, какое вещество является окислителем, ка-кое восстановителем; какое вещество окисляется, какое - восстанавливается.
Реакции выражаются схемами:
KClO3 + H2SO4 + FeSO4 → KCl + H2O + Fe2(SO4)3
Zn + HNO3 → Zn(NO3)2 + H2O + N2O
Составьте электронные уравнения. Расставьте коэффициенты в уравнениях реакций. Для каждой реакции укажите, какое вещество является окислителем, ка-кое восстановителем; какое вещество окисляется, какое - восстанавливается.
Обсуждение
Неизвестный
12.03.2011, 11:01
общий
это ответ
Здравствуйте, Посетитель - 366683!
1. Хлорат-ион является окислителем, восстанавливается до хлорид-иона. Ион двухвалентного железа восстановитель – окисляется до железа в степени окисления III. Реакция проходит в среде серной кислоты
ClO3- + 6H+ + 6е → Cl- + 3H2O – процесс восстановления
Fe2+ - е = Fe3+ - процесс окисления
Чтобы число принятых электронов стало равным числу отданных электронов, умножаем вторую полуреакцию на 6, суммарно получаем
KClO3 + 6FeSO4 +3H2SO4→ KCl + 3Fe2(SO4)3+ 3H2O
2. Окислитель азотная кислота, восстанавливается до оксида азота(I). Восстановитель металлический цинк, окисляется до иона цинка с зарядом 2+
2NO3- +10H+ + 8е → N2O + 5H2O
Zn -2е→ Zn2+
Чтобы число принятых электронов стало равным числу отданных электронов, умножаем вторую полуреакцию на 4 , суммарно получаем
4Zn + 10HNO3 → 4Zn(NO3)2 + N2O + 5H2O
1. Хлорат-ион является окислителем, восстанавливается до хлорид-иона. Ион двухвалентного железа восстановитель – окисляется до железа в степени окисления III. Реакция проходит в среде серной кислоты
ClO3- + 6H+ + 6е → Cl- + 3H2O – процесс восстановления
Fe2+ - е = Fe3+ - процесс окисления
Чтобы число принятых электронов стало равным числу отданных электронов, умножаем вторую полуреакцию на 6, суммарно получаем
KClO3 + 6FeSO4 +3H2SO4→ KCl + 3Fe2(SO4)3+ 3H2O
2. Окислитель азотная кислота, восстанавливается до оксида азота(I). Восстановитель металлический цинк, окисляется до иона цинка с зарядом 2+
2NO3- +10H+ + 8е → N2O + 5H2O
Zn -2е→ Zn2+
Чтобы число принятых электронов стало равным числу отданных электронов, умножаем вторую полуреакцию на 4 , суммарно получаем
4Zn + 10HNO3 → 4Zn(NO3)2 + N2O + 5H2O
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