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Задать вопрос экспертам

Консультация № 182470

11.03.2011, 21:45

71.37 руб.

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Образование

Уважаемые эксперты! Пожалуйста, ответьте на вопрос
На основании стандартных теплот образования и абсолютных стандарт-ных энтропий соответствующих веществ вычислите ΔG0 реакции, протекающей по уравнению
CO(г) + 3H2(г) = CH4(г) + H2O(г) .
Возможна ли эта реакция при стандартных условиях?

Обсуждение

Неизвестный

12.03.2011, 00:04

общий

это ответ

Здравствуйте, Посетитель - 366683!
По закону Гесса:
ΔH⁰_х.р.=ΔH⁰_{H2O (г)} + ΔH⁰_{СH4 (г)} - 3 ΔH⁰_{H2 (г)} - ΔH⁰_{CO (г)}=
=-241.83 кДж + (-74.85кДж) - 3*0 - (-110.53кДж) = -206,15кДж

ΔS⁰_х.р.=S⁰_{H2O (г)} + S⁰_{СH4 (г)} - 3 S⁰_{H2 (г)} - S⁰_{CO (г)}=
=188.72 кДж + 186,19 Дж/К - 3*130.59 Дж/К - 197.91 Дж/K = -214.77 Дж/К

ΔG=ΔH-T*ΔS = -206150 Дж -298К * (-214,77Дж/К) = -142149 Дж ~ -142.15 кДж
Так как ΔG<0, то данная реакция возможна при стандартных условиях.

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