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Консультация № 177440

24.03.2010, 17:29

43.11 руб.

0 2 1

Образование

Исходя из степени окисления в следующих окислительно-восстановительных реакциях найдите окислитель и восстановитель.
Составьте электронные уравнения процессов окисления и восстановления. На основании окислительно-восстановительных потенциалов определите направление протекания реакций.
FeS+HNO3 -> Fe(NO3)2 + S + NO + H2O
MnO2 + Na2SO4 + KOH -> KMnSO4 + Na2SO3 + H2O

Обсуждение

Неизвестный

24.03.2010, 23:54

общий

это ответ

Здравствуйте, Эдик В.

FeS+2HNO₃ -> Fe(NO₃)₂ + S + NO + H₂O

Fe²⁺ + S^2- + H⁺ + NO₃^- -> Fe²⁺ + NO₃^- + S + NO + O^2- + H⁺
Вычёркиваем , что не изменяется - получаем:
3S^2- + 2NO₃^- -> 3S + 4O^2- + 2NO
Окислитель азот, восстановитель - сера:
3S^2- + 2N⁵⁺ -> 3S + 2N²⁺

Возможно, у вас опечатка
(потому то в противном случае и сера и марганец являются окислителями, а восстановителя нет - получается бессмыслица):
MnO₂ + Na₂SO₄ + KOH -> KMnSO₄ + Na₂SO₃ + H₂O

Mn⁴⁺ + O^2- + Na⁺ + SO₄^2- + K⁺ + OH^- -> K⁺ + MnO₄^- + Na⁺ + SO₃^2- + H⁺ + O^2-

2Mn⁴⁺ +3SO₄^2- + 5O^2- -> 2MnO₄^- + 3SO₃^2-
Окислитель сера, восстановитель - марганец:
2Mn⁴⁺ +3S⁶⁺ -> 2Mn⁷⁺ + 3S⁴⁺

Неизвестный

27.03.2010, 23:37

общий

Ну скажите хотя бы, что всё неправильно...

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