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Консультация № 163431
27.03.2009, 23:02
0.00 руб.
0
1
1
Здравствуйте!!!Помогите пожалуйста с задачей....При воздействии вольфрама калия K2WO4 с соляной кислотой выпадает осадок вольфрамовой кислоты H2WO4. Написать уравнение реакции. Какой объём при температуре 127 С и давления 150 кПа будет занимать хлористый водород, пошедший на приготовление 20% (по массе) соляной кислоты, и каков объём использованной воды, если количество выпавшего осадка равно 2,5 моль?
Обсуждение
27.03.2009, 23:21
общий
это ответ
Здравствуйте, Лаптев Антон Анатольевич!
K2WO4+2HCl[$8594$]H2WO4[$8595$]+2KCl
n(H2WO4)=2,5 моль
n(HCl)=2n(H2WO4)=5 моль
V(HCl)=n(HCl)*R*T/p=5моль*8,314Дж/(моль*К)*400К/150кПа=111 л
m(HCl)=n(HCl)*M(HCl)=5моль*35,5г/моль=177,5 г
[$969$]=m(HCl)/(m(HCl)+m(H2O))
m(H2O)=m(HCl)/[$969$]-m(HCl)=177,5/0,2-177,5=710 г
V(H2O)=m(H2O)*[$961$]=710 мл
K2WO4+2HCl[$8594$]H2WO4[$8595$]+2KCl
n(H2WO4)=2,5 моль
n(HCl)=2n(H2WO4)=5 моль
V(HCl)=n(HCl)*R*T/p=5моль*8,314Дж/(моль*К)*400К/150кПа=111 л
m(HCl)=n(HCl)*M(HCl)=5моль*35,5г/моль=177,5 г
[$969$]=m(HCl)/(m(HCl)+m(H2O))
m(H2O)=m(HCl)/[$969$]-m(HCl)=177,5/0,2-177,5=710 г
V(H2O)=m(H2O)*[$961$]=710 мл
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