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Консультация № 109789
17.11.2007, 06:21
0.00 руб.
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1
Зравствуйте! Вот такая задача:
Энергия активации реакции равна 103,5 кДж/моль. Константа скорости этой реакции при 298 К равна 2,03•10<sup>-3</sup>. Вычислите константу скорости этой реакции при 288 К.
Буду благодарен за решение.
Энергия активации реакции равна 103,5 кДж/моль. Константа скорости этой реакции при 298 К равна 2,03•10<sup>-3</sup>. Вычислите константу скорости этой реакции при 288 К.
Буду благодарен за решение.
Обсуждение
Неизвестный
17.11.2007, 08:07
общий
это ответ
Здравствуйте, piit!
Сначала надо найти предэкспоненциальный множитель k<sub>0</sub>. Формула:
k = k<sub>0</sub>•e<sup>-E/RT</sup>
2,03•10<sup>-3</sup> = k<sub>0</sub>•e<sup>-103500/(8.31•298)</sup>
k<sub>0</sub> = 2.876•10<sup>15</sub>
Теперь надо проделать вычисления в обратную сторону:
k = 2.876•10<sup>15</sub>•e<sup>-103500/(8.31•288)</sup> = 4.756•10<sup>-4</sup>
Ну вот Вам и ответ:)
Сначала надо найти предэкспоненциальный множитель k<sub>0</sub>. Формула:
k = k<sub>0</sub>•e<sup>-E/RT</sup>
2,03•10<sup>-3</sup> = k<sub>0</sub>•e<sup>-103500/(8.31•298)</sup>
k<sub>0</sub> = 2.876•10<sup>15</sub>
Теперь надо проделать вычисления в обратную сторону:
k = 2.876•10<sup>15</sub>•e<sup>-103500/(8.31•288)</sup> = 4.756•10<sup>-4</sup>
Ну вот Вам и ответ:)
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