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Консультация № 188608
07.01.2016, 17:45
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Здравствуйте! Прошу помощи в следующем вопросе:
Как изменится скорость реакции:
Fe2O3(к) + 3 СО(г) ↔ 2 Fe(к) + 3СО2(г) ,
если
а) увеличить объем системы в 3 раза?
б) увеличить давление в системе в 5 раз?
Как изменится скорость реакции:
Fe2O3(к) + 3 СО(г) ↔ 2 Fe(к) + 3СО2(г) ,
если
а) увеличить объем системы в 3 раза?
б) увеличить давление в системе в 5 раз?
Обсуждение
07.01.2016, 18:50
общий
это ответ
Здравствуйте, eskimovisage1488!
Для начала разберёмся с молекулярностью реакции. Очевидно, что она практически никогда не соответствует таким коэффициентам.
Скорее всего, элементарным процессом как прямой так и обратной реакции является взаимодействие отдельных молекул газа с поверхностью твёрдых частиц. Таким образом реакция одномолекулярна по реагирующему газу и её скорость прямо пропорциональна давлению.
а) увеличение объёма в 3 раза уменьшит давление и скорость реакции в 3 раза
б) увеличение давления в 5 раз увеличит скорость реакции в 5 раз
При этом изменение давления одинаково влияет на скорость как прямой так и обратной реакции, не изменяя равновесие.
Для начала разберёмся с молекулярностью реакции. Очевидно, что она практически никогда не соответствует таким коэффициентам.
Скорее всего, элементарным процессом как прямой так и обратной реакции является взаимодействие отдельных молекул газа с поверхностью твёрдых частиц. Таким образом реакция одномолекулярна по реагирующему газу и её скорость прямо пропорциональна давлению.
а) увеличение объёма в 3 раза уменьшит давление и скорость реакции в 3 раза
б) увеличение давления в 5 раз увеличит скорость реакции в 5 раз
При этом изменение давления одинаково влияет на скорость как прямой так и обратной реакции, не изменяя равновесие.
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