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Консультация № 188609
07.01.2016, 17:46
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Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
Константа равновесия реакции:
PCl5 ↔ PCl3 + Cl2
равна 0,63 при 500оС. Исходная концентрация PCl5 равна 1,2 моль/л. Рассчитайте равновесные концентрации PCl3 и Cl2 .
Константа равновесия реакции:
PCl5 ↔ PCl3 + Cl2
равна 0,63 при 500оС. Исходная концентрация PCl5 равна 1,2 моль/л. Рассчитайте равновесные концентрации PCl3 и Cl2 .
Обсуждение
07.01.2016, 19:06
общий
это ответ
Здравствуйте, eskimovisage1488!
Видимо, предполагается что все вещества при указанных условиях газообразны, а константа равновесия выражена через концентрации.
[PCl3][Cl2]/[PCl5]=0,63 M
при этом, если изначально имеется 1,2 M PCl5, то
[PCl3]=[Cl2]
[PCl3]+[PCl5]=1,2 M
отсюда
[PCl3]2/(1,2 M-[PCl3])=0,63 M
решая квадратное уравнение, находим
[PCl3]=[Cl2]=0,61 M
[PCl5]=0,59 M
Видимо, предполагается что все вещества при указанных условиях газообразны, а константа равновесия выражена через концентрации.
[PCl3][Cl2]/[PCl5]=0,63 M
при этом, если изначально имеется 1,2 M PCl5, то
[PCl3]=[Cl2]
[PCl3]+[PCl5]=1,2 M
отсюда
[PCl3]2/(1,2 M-[PCl3])=0,63 M
решая квадратное уравнение, находим
[PCl3]=[Cl2]=0,61 M
[PCl5]=0,59 M
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