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Консультация № 190318
20.12.2016, 01:13
0.00 руб.
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Здравствуйте! У меня возникли сложности с таким вопросом:
1) дана реакция 2FeO(k)+2SO²(r)=2FeS(k)+3O²(r) рассчитать стандартную энергию Гиббса реакции при температурах25°С и 900°С. Для каждой температуры сделать вывод о возможности самопроизвольного протекания реакции. Определить температурный область самопроизвольного протекания реакции.
2) дана реакция 2FeS(k)+3O²(r)=2FeO(k)+2SO²(r). Записать кинетической уравнение реакции и определить ее теоретический порядок. Определить как изменится скорость реакции: а) при увеличении объема в 4*раза; б) при уменьшении температуры на 30°, считая значение температурного коэффициента скорости реакции равным 2.
3). Для приведенной во второй задаче обратимой гетерогенной реакции, записать выражения констант равновесия Кс и Кр. Определить численные значения Кс и Кр при температурах указанных во второй задаче.
4). Для обратимой гетерогенной реакции, выраженной уравнение Fe²O³(k)+3H²(r)<=>2Fe(k)+³H²O(r);∆H<0, определить направление сдвига равновесия,если:а). Увеличивается концентрация разнообразного вещества реагента; б) увеличивается давление; в) уменьшается температура
1) дана реакция 2FeO(k)+2SO²(r)=2FeS(k)+3O²(r) рассчитать стандартную энергию Гиббса реакции при температурах25°С и 900°С. Для каждой температуры сделать вывод о возможности самопроизвольного протекания реакции. Определить температурный область самопроизвольного протекания реакции.
2) дана реакция 2FeS(k)+3O²(r)=2FeO(k)+2SO²(r). Записать кинетической уравнение реакции и определить ее теоретический порядок. Определить как изменится скорость реакции: а) при увеличении объема в 4*раза; б) при уменьшении температуры на 30°, считая значение температурного коэффициента скорости реакции равным 2.
3). Для приведенной во второй задаче обратимой гетерогенной реакции, записать выражения констант равновесия Кс и Кр. Определить численные значения Кс и Кр при температурах указанных во второй задаче.
4). Для обратимой гетерогенной реакции, выраженной уравнение Fe²O³(k)+3H²(r)<=>2Fe(k)+³H²O(r);∆H<0, определить направление сдвига равновесия,если:а). Увеличивается концентрация разнообразного вещества реагента; б) увеличивается давление; в) уменьшается температура
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