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Консультация № 186584
02.09.2012, 18:37
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Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
Вычислите массу осадка, образующегося при взаимодействии трех молей CoCl3•5NH3 c избытком раствора AgNO3. (Отв: 861 г)
Вычислите массу осадка, образующегося при взаимодействии трех молей CoCl3•5NH3 c избытком раствора AgNO3. (Отв: 861 г)
Обсуждение
04.09.2012, 15:01
общий
это ответ
Здравствуйте, Massimo!
Сперва определим координационную формулу комплекса, учитывая, что аммиак может находиться только во внутренней сфере, а координационное число трёхвалентного хрома равно 6.
[Co(NH3)5Cl]Cl2
В этом случае уравнение реакции
[Co(NH3)5Cl]Cl2+2AgNO3=[Co(NH3)5Cl](NO3)2+2AgCl[$8595$]
Как видно из уравнения, на 1 моль комплекса приходится 2 моля осадка хлорида серебра
nAgCl=3*2=6 моль
mAgCl=nAgCl*MAgCl=6моль*143,5г/моль=861 г
Сперва определим координационную формулу комплекса, учитывая, что аммиак может находиться только во внутренней сфере, а координационное число трёхвалентного хрома равно 6.
[Co(NH3)5Cl]Cl2
В этом случае уравнение реакции
[Co(NH3)5Cl]Cl2+2AgNO3=[Co(NH3)5Cl](NO3)2+2AgCl[$8595$]
Как видно из уравнения, на 1 моль комплекса приходится 2 моля осадка хлорида серебра
nAgCl=3*2=6 моль
mAgCl=nAgCl*MAgCl=6моль*143,5г/моль=861 г
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