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Консультация № 68467
25.12.2006, 04:00
0.00 руб.
0
1
1
Добрый вечер, ночь ))
помогите, плиZZ:
CrCl3+KIO+H2SO4=
Al+KClO3+H2SO4=
HBrO3+H2S=
H2O2+S+NaOH=
H3PO2+KMnO4+H2SO4=
NaOH+H2O+P=
Приложение:
оЧ нанда !!!!!!!!
помогите, плиZZ:
CrCl3+KIO+H2SO4=
Al+KClO3+H2SO4=
HBrO3+H2S=
H2O2+S+NaOH=
H3PO2+KMnO4+H2SO4=
NaOH+H2O+P=
Приложение:
оЧ нанда !!!!!!!!
Обсуждение
Неизвестный
25.12.2006, 20:36
общий
это ответ
Здравствуйте, BUT!
1) не совсем уверен что реакция пойдёт, т.к. для окисления хрома в вкислой среде надо очень сильный окислитель, а бромноватистая кислота наверно не дотягивает по силе.
ну если пойдёт, то будет что-то вида:
CrCl3 + KIO + H2SO4 -> H2Cr2O7 + I2 + KCl (+ H2O с какой-то строны...)
2) алюмний наверно перейдёт в соль, а хлор перейдёт в степень окисления -1:
Al+KClO3+H2SO4= Al2(SO4)3 + KCl + H2O
3) бром окисляет серу, будет что-то вида:
HBrO3+H2S= H2SO3+ HBr
4) я предполагаю что серу будет окислять пероксид:
H2O2+S+NaOH= Na2SO3 + H2O
5)фосфор с +1 окислится до +3, марганец восстановится с +7 до +2:
H3PO2+KMnO4+H2SO4= H3PO3+ MnSO4+ K2SO4 (может с какой-то стороны надо ещё воду)
6) при нагревании в растворах щелочей фосфор диспропорционирует (сначала все атомы в стетпени окисления 0, потом 1 атом отбирает у остальных 3-х по электрону, получает степень -3 (фосфин), а три остальных идут на образование соли). Предполагаем что фосфор в виде белого фосфора, молекулы Р4:
3*NaOH+3*H2O+P4= РН3 + 3*NaH2PO2
1) не совсем уверен что реакция пойдёт, т.к. для окисления хрома в вкислой среде надо очень сильный окислитель, а бромноватистая кислота наверно не дотягивает по силе.
ну если пойдёт, то будет что-то вида:
CrCl3 + KIO + H2SO4 -> H2Cr2O7 + I2 + KCl (+ H2O с какой-то строны...)
2) алюмний наверно перейдёт в соль, а хлор перейдёт в степень окисления -1:
Al+KClO3+H2SO4= Al2(SO4)3 + KCl + H2O
3) бром окисляет серу, будет что-то вида:
HBrO3+H2S= H2SO3+ HBr
4) я предполагаю что серу будет окислять пероксид:
H2O2+S+NaOH= Na2SO3 + H2O
5)фосфор с +1 окислится до +3, марганец восстановится с +7 до +2:
H3PO2+KMnO4+H2SO4= H3PO3+ MnSO4+ K2SO4 (может с какой-то стороны надо ещё воду)
6) при нагревании в растворах щелочей фосфор диспропорционирует (сначала все атомы в стетпени окисления 0, потом 1 атом отбирает у остальных 3-х по электрону, получает степень -3 (фосфин), а три остальных идут на образование соли). Предполагаем что фосфор в виде белого фосфора, молекулы Р4:
3*NaOH+3*H2O+P4= РН3 + 3*NaH2PO2
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