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Консультация № 197007
08.11.2019, 17:23
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Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
Осуществите следующие превращения:
а) СН2 = СН – СН = СН2 → ClCH2 – CHBr – CHBr – CH3;
б) СН2 = СН – СН = СН2 → BrCH2 – СН2 – СНCl – СН2Br
Осуществите следующие превращения:
а) СН2 = СН – СН = СН2 → ClCH2 – CHBr – CHBr – CH3;
б) СН2 = СН – СН = СН2 → BrCH2 – СН2 – СНCl – СН2Br
Обсуждение
09.11.2019, 00:28
общий
это ответ
Здравствуйте, kholostova!
Первое присоединение к бутадиену происходит в позициях 1 и 4, поэтому порядок реакций следующий
а) СН2=СН–СН=СН2 + HCl = ClСН2-СН=СН-СН3
ClСН2-СН=СН-СН3 + Br2 = ClСН2-СНBr-СНBr-СН3
б) СН2=СН–СН=СН2 + Br2 = BrСН2-СН=СН-СН2Br
BrСН2-СН=СН-СН2Br + HCl = BrСН2-СН2-СНCl-СН2Br
Первое присоединение к бутадиену происходит в позициях 1 и 4, поэтому порядок реакций следующий
а) СН2=СН–СН=СН2 + HCl = ClСН2-СН=СН-СН3
ClСН2-СН=СН-СН3 + Br2 = ClСН2-СНBr-СНBr-СН3
б) СН2=СН–СН=СН2 + Br2 = BrСН2-СН=СН-СН2Br
BrСН2-СН=СН-СН2Br + HCl = BrСН2-СН2-СНCl-СН2Br
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