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Консультация № 195603
13.05.2019, 08:49
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Здравствуйте! Прошу помощи в следующем вопросе:
При температуре 298К наиболее вероятно протекание реакции:
Реакция
dG°298, кДж/моль
1)C (графит) + CO2 (г.) = 2CO (г.)
120,2
2)C (графит) + ½ O2 (г.) = CO (г.)
-137,1
3)C (графит) + O2 (г.) = CO2 (г.)
-394,4
4)C (графит) + 2H2 (г.) = CH4 (г.)
-50,8
При температуре 298К наиболее вероятно протекание реакции:
Реакция
dG°298, кДж/моль
1)C (графит) + CO2 (г.) = 2CO (г.)
120,2
2)C (графит) + ½ O2 (г.) = CO (г.)
-137,1
3)C (графит) + O2 (г.) = CO2 (г.)
-394,4
4)C (графит) + 2H2 (г.) = CH4 (г.)
-50,8
Обсуждение
13.05.2019, 09:22
общий
это ответ
Здравствуйте, Valeriya!
С чисто термодинамической точки зрения, наиболее вероятно протекание реакции с наиболее отрицательной энергией Гиббса - то есть третьей реакции, окисления графита до углекислого газа. Правда, если брать в расчёт кинетику, при комнатной температуре ни одна из этих реакций не протекает со сколько-нибудь значительной скоростью
С чисто термодинамической точки зрения, наиболее вероятно протекание реакции с наиболее отрицательной энергией Гиббса - то есть третьей реакции, окисления графита до углекислого газа. Правда, если брать в расчёт кинетику, при комнатной температуре ни одна из этих реакций не протекает со сколько-нибудь значительной скоростью
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