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Консультация № 193737
20.10.2018, 20:42
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20.10.2018, 22:17
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это ответ
Здравствуйте, svrvsvrv!
Геометрическая изомерия по двойной связи возможна только в случае, если каждый из атомов, связанных двойной связью, имеет различные группы (заместители, продолжение главной цепочки, водород; также возможен асимметричный цикл) на остальных двух связях - то есть, перевернув связь мы не получим совпадающее с исходным соединение.
Из приведённых примеров этому соответствуют варианты б) и г)
Остальные не образуют цис-транс изомеров, поскольку:
а) 2 хлора на первом атоме и 2 водорода на втором
в) 2 метил-группы на втором атоме (начало главной цепочки и заместитель)
д) 2 брома на первом атоме
Геометрическая изомерия по двойной связи возможна только в случае, если каждый из атомов, связанных двойной связью, имеет различные группы (заместители, продолжение главной цепочки, водород; также возможен асимметричный цикл) на остальных двух связях - то есть, перевернув связь мы не получим совпадающее с исходным соединение.
Из приведённых примеров этому соответствуют варианты б) и г)
Остальные не образуют цис-транс изомеров, поскольку:
а) 2 хлора на первом атоме и 2 водорода на втором
в) 2 метил-группы на втором атоме (начало главной цепочки и заместитель)
д) 2 брома на первом атоме
5
Большое спасибо за подробный ответ!
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