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Консультация № 193639
02.10.2018, 17:01
0.00 руб.
02.10.2018, 19:52
1
5
1
Здравствуйте, уважаемые эксперты! Прошу вас ответить на следующий вопрос:
Могут ли изомеры C4H8Br2 быть следующими:
Могут ли изомеры C4H8Br2 быть следующими:
Прикрепленные файлы:
Обсуждение
02.10.2018, 19:58
общий
это ответ
Здравствуйте, svrvsvrv!
Если не считать замечания о том, что если подписываете атомы углерода, то и водород нужно приписывать, Вы успешно идентифицировали почти все изомеры.
Единственная ошибка: структуры №4 и №8 идентичны - это 2,3-дибромбутан.
И у Вас отсутствует ещё один изомер - 1,4-дибромбутан
Если не считать замечания о том, что если подписываете атомы углерода, то и водород нужно приписывать, Вы успешно идентифицировали почти все изомеры.
Единственная ошибка: структуры №4 и №8 идентичны - это 2,3-дибромбутан.
И у Вас отсутствует ещё один изомер - 1,4-дибромбутан
5
03.10.2018, 15:13
общий
Адресаты:
4-е соединение называется 2,3-дибромбутан, а 8-е - 1,2-дибром-1,2-диметилэтан. Значит, всё-таки можно сказать, что эти изомеры неидентичны?
03.10.2018, 18:48
общий
Адресаты:
Нет такого соединения "1,2-дибром-1,2-диметилэтан"! И вообще, 1,2-диметилэтан тоже не бывает.
В более сложных случаях возможны различные варианты выбора главной цепи атомов углерода, но никогда на её концах не окажутся присоединены заместители, являющиеся цепочками атомов углерода - они автоматически окажутся включены в главную цепь.
В данном случае возможно провести главную цепь через все 4 атома углерода, так что соединение является производной бутана. Атомы брома присоединены во второй и третьей позициях, поэтому это 2,3-дибромбутан.
Аналогично, соединение под номером 9 - это 2,2-дибромбутан (здесь выбираем нумерацию атомов с того конца, к которому ближе заместители)
В более сложных случаях возможны различные варианты выбора главной цепи атомов углерода, но никогда на её концах не окажутся присоединены заместители, являющиеся цепочками атомов углерода - они автоматически окажутся включены в главную цепь.
В данном случае возможно провести главную цепь через все 4 атома углерода, так что соединение является производной бутана. Атомы брома присоединены во второй и третьей позициях, поэтому это 2,3-дибромбутан.
Аналогично, соединение под номером 9 - это 2,2-дибромбутан (здесь выбираем нумерацию атомов с того конца, к которому ближе заместители)
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