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Задать вопрос экспертам

Консультация № 162849

21.03.2009, 12:55

0.00 руб.

0 1 1

Образование

Здравствуйте уважаемые эусперты, нужна помощь в решении задачки

Составьте схему гальванического элемента, в основе которого лежит реакция, протекающая по уравнению
Ni + Pb(NO3)2 = Ni(NO3)2 + Pb
Напишите электронные уравнения анодного и катодного процессов. Вычислите ЭДС этого элемента, если [Ni^2+]=0,01 моль/л ,
[Pb^2+]=0,0001 моль/л. Ответ:0,064В.

заранее большое спасибо

Обсуждение

давно

Roman Chaplinsky / Химик CH

Модератор
156417
2175

21.03.2009, 13:50

общий

это ответ

Здравствуйте, Kirieshka!
Ni|Ni(NO3)2||Pb(NO3)2|Pb
A(-) Ni-2e^-=Ni²⁺
K(+) Pb²⁺+2e^-=Pb

E=[$966$](Pb²⁺/Pb)-[$966$](Ni²⁺/Ni)+RT/(ZF)*ln([Pb²⁺]/[Ni²⁺])=
=-0,1262В-(-0,257В)+8,314Дж/(моль*К)*298К/(96500Кл/моль*2)*ln(0,0001/0,01)=0,0717 В

Различие с Вашим результатом обусловлено неодинаковыми значениями табличных данных в разных источниках

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