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Консультация № 67873
20.12.2006, 18:58
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Здравствуйте, уважаемые эксперты!Пожалуйста ответьте на вопрос, как зависит выход продуктов в результате реакции гидрирования от повышения общего давления системы и почему?Заранее благодарен
Обсуждение
Неизвестный
22.12.2006, 02:24
общий
это ответ
Здравствуйте, Solo!
В соответствии с принципом Ле-Шателье система стремится скомпенсировать воздействие на неё извне, в данном случае-повышение давления. Рассмотрим реакцию гидрирования:
CxHy+zH2---->CxH(y+2z) Считаем суммарные кол-ва вещества(а объем прямо пропорцио
x+z моль x моль нален кол-ву вещ-ва) в правой и левой части.
Повышение давления компенсируется уменьшением объема и т.к. в реакции суммарный объем реагентов уменьшается равновесие смещается вправо т.е. выход увеличивается.
С уважением, IceW0|f.
В соответствии с принципом Ле-Шателье система стремится скомпенсировать воздействие на неё извне, в данном случае-повышение давления. Рассмотрим реакцию гидрирования:
CxHy+zH2---->CxH(y+2z) Считаем суммарные кол-ва вещества(а объем прямо пропорцио
x+z моль x моль нален кол-ву вещ-ва) в правой и левой части.
Повышение давления компенсируется уменьшением объема и т.к. в реакции суммарный объем реагентов уменьшается равновесие смещается вправо т.е. выход увеличивается.
С уважением, IceW0|f.
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