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Консультация № 196868
29.10.2019, 15:22
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Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
К смеси двух одноосновных карбоновых кислот, одна из которых не содержит первичных атомов углерода, а вторая не содержит вторичных атомов углерода, добавили избыток концентрированного раствора NaOH. Раствор упарили, осадок прокалили со щёлочью и получили 789 мл газа А (25*C, 1 атм.), 7.8 г. жидкости Б и твердый остаток, при добавлении к которому избытка серной кислоты выделилось 2.936 л. газа В (25*C, 1 атм.). Плотность смеси газов А и В по неону составила 2.3. Установите строение и массы кислот. Предложите способ получения 5-бромсалициловой ( 5-бром 2-гидроксибензойной) кислоты из вещества Б с использованием только неорганических реагентов. Напишите уравнения протекающих реакций.
К смеси двух одноосновных карбоновых кислот, одна из которых не содержит первичных атомов углерода, а вторая не содержит вторичных атомов углерода, добавили избыток концентрированного раствора NaOH. Раствор упарили, осадок прокалили со щёлочью и получили 789 мл газа А (25*C, 1 атм.), 7.8 г. жидкости Б и твердый остаток, при добавлении к которому избытка серной кислоты выделилось 2.936 л. газа В (25*C, 1 атм.). Плотность смеси газов А и В по неону составила 2.3. Установите строение и массы кислот. Предложите способ получения 5-бромсалициловой ( 5-бром 2-гидроксибензойной) кислоты из вещества Б с использованием только неорганических реагентов. Напишите уравнения протекающих реакций.
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