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Консультация № 189149
10.04.2016, 11:52
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Здравствуйте! Прошу помощи в следующем вопросе: К 5 каплям перманганата калия добавили 2 капли серной кислоты. Затем добавили по каплям ,до обесцвечивания, раствор гесацианоферрата II калия. Написать молекулярные ионное уравнения реакций учитывая, что комлекс железа II переходит в комплекс железа III с тем же координационным числом , а перманганат калия восстанавливается в кислой среде до сульфата марганцаII
Обсуждение
11.04.2016, 00:00
общий
это ответ
Здравствуйте, samstep.stepanov!
Окисление гексацианоферрата
[Fe(CN)6]4--e-=[Fe(CN)6]3-
Восстановление перманганата
MnO4-+8H++5e-=Mn2++4H2O
Совмещая эти уравнения, получаем
5[Fe(CN)6]4-+MnO4-+8H+=5[Fe(CN)6]3-+Mn2++4H2O
или в молекулярной форме
5K4[Fe(CN)6]+KMnO4+4H2SO4=5K3[Fe(CN)6]+MnSO4+3K2SO4+4H2O
Окисление гексацианоферрата
[Fe(CN)6]4--e-=[Fe(CN)6]3-
Восстановление перманганата
MnO4-+8H++5e-=Mn2++4H2O
Совмещая эти уравнения, получаем
5[Fe(CN)6]4-+MnO4-+8H+=5[Fe(CN)6]3-+Mn2++4H2O
или в молекулярной форме
5K4[Fe(CN)6]+KMnO4+4H2SO4=5K3[Fe(CN)6]+MnSO4+3K2SO4+4H2O
5
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