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Консультация № 187531
04.09.2013, 13:08
100.51 руб.
0
3
1
Здравствуйте! Прошу помощи в следующих вопросах,задачу желательно подробно.
Обсуждение
Неизвестный
04.09.2013, 13:34
общий
Первый вопрос
Третий закон или третье начало термодинамики: энтропия любой равновесной системы при абсолютном нуле температуры всегда равна нулю.
Формулу
dS/dT = C/T
применяют для практического определения абсолютного значения энтропии при температуре Т, используя постулат Планка и значения теплоёмкости С, теплот и температур фазовых переходов в интервале от 0 до Т К.
Второй вопрос
1 Изменение энтропии при фазовом переходе равно:
ΔS1 = ΔH/Tпл = Н*m/Тпл = 194*30/289,6 = 20,1 Дж/К.
2 Изменение энтропии при нагреве от Тпл до Т найдется по формуле:
ΔS2 = Ср*m*ln(T/Tпл) = 2,19*30*ln(333/289,6) = 9,17 Дж/К.
3 Тогда общее изменение энтропии составит:
ΔS = ΔS1 + ΔS2 = 20,1 + 9,17 = 29,27 Дж/К.
Ответ: ΔS = 29,27 Дж/К.
Третий закон или третье начало термодинамики: энтропия любой равновесной системы при абсолютном нуле температуры всегда равна нулю.
Формулу
dS/dT = C/T
применяют для практического определения абсолютного значения энтропии при температуре Т, используя постулат Планка и значения теплоёмкости С, теплот и температур фазовых переходов в интервале от 0 до Т К.
Второй вопрос
1 Изменение энтропии при фазовом переходе равно:
ΔS1 = ΔH/Tпл = Н*m/Тпл = 194*30/289,6 = 20,1 Дж/К.
2 Изменение энтропии при нагреве от Тпл до Т найдется по формуле:
ΔS2 = Ср*m*ln(T/Tпл) = 2,19*30*ln(333/289,6) = 9,17 Дж/К.
3 Тогда общее изменение энтропии составит:
ΔS = ΔS1 + ΔS2 = 20,1 + 9,17 = 29,27 Дж/К.
Ответ: ΔS = 29,27 Дж/К.
04.09.2013, 16:27
общий
Пожалуйста, отправьте ответ через форму отправки ответа (внизу вопроса должна быть ссылка 'ответить')
Неизвестный
04.09.2013, 17:51
общий
это ответ
Здравствуйте, карлос!
Первый вопрос
Третий закон или третье начало термодинамики: энтропия любой равновесной системы при абсолютном нуле температуры всегда равна нулю.
Формулу
dS/dT = C/T
применяют для практического определения абсолютного значения энтропии при температуре Т, используя постулат Планка и значения теплоёмкости С, теплот и температур фазовых переходов в интервале от 0 до Т К.
Второй вопрос
1 Изменение энтропии при фазовом переходе равно:
ΔS1 = ΔH/Tпл = Н*m/Тпл = 194*30/289,6 = 20,1 Дж/К.
2 Изменение энтропии при нагреве от Тпл до Т найдется по формуле:
ΔS2 = Ср*m*ln(T/Tпл) = 2,19*30*ln(333/289,6) = 9,17 Дж/К.
3 Тогда общее изменение энтропии составит:
ΔS = ΔS1 + ΔS2 = 20,1 + 9,17 = 29,27 Дж/К.
Ответ: ΔS = 29,27 Дж/К.
Первый вопрос
Третий закон или третье начало термодинамики: энтропия любой равновесной системы при абсолютном нуле температуры всегда равна нулю.
Формулу
dS/dT = C/T
применяют для практического определения абсолютного значения энтропии при температуре Т, используя постулат Планка и значения теплоёмкости С, теплот и температур фазовых переходов в интервале от 0 до Т К.
Второй вопрос
1 Изменение энтропии при фазовом переходе равно:
ΔS1 = ΔH/Tпл = Н*m/Тпл = 194*30/289,6 = 20,1 Дж/К.
2 Изменение энтропии при нагреве от Тпл до Т найдется по формуле:
ΔS2 = Ср*m*ln(T/Tпл) = 2,19*30*ln(333/289,6) = 9,17 Дж/К.
3 Тогда общее изменение энтропии составит:
ΔS = ΔS1 + ΔS2 = 20,1 + 9,17 = 29,27 Дж/К.
Ответ: ΔS = 29,27 Дж/К.
5
Спасибо!
Форма ответа
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