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Консультация № 186484
31.07.2012, 14:19
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Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
Квантовые числа для электронов внешнего энергетического уровня атома некоторого элемента имеют следующие значения: n = 5, l = 0, ml= 0, ms = + 1/2. Сколько свободных 4d-орбиталей содержит атом данного элемента. Напишите электронную формулу данного атома?
Квантовые числа для электронов внешнего энергетического уровня атома некоторого элемента имеют следующие значения: n = 5, l = 0, ml= 0, ms = + 1/2. Сколько свободных 4d-орбиталей содержит атом данного элемента. Напишите электронную формулу данного атома?
Обсуждение
Неизвестный
31.07.2012, 22:55
общий
это ответ
И снова здравствуйте, Massimo!
В ответе на вопрос №186482 я уже описал квантовые числа. Не будем снова описывать их.
Согласно принципу Паули в атоме не может быть двух электронов с одинаковым набором квантовых чисел. Значит, набор n = 5, l = 0, ml= 0, ms = +1/2 соответствует только одному электрону. Значит, у этого элемента ровно 1 электрон на 5s (т.к. n = 5, l = 0) подуровне. Таких элементов 2: рубидий и серебро (т.к. у серебра есть провал с 5s на 4d-подуровень). Причём у рубидия все 4d-орбитали свободны (5 орбиталей) (они ещё не заполнялись, объяснение того, что орбиталей 5 - см. вопрос №186482), а у серебра все 4d-орбитали заняты (т.к. есть провал электрона).
Электронные формулы серебра и рубидия:
Rb: 1s22s22p63s23p64s23d104p65s1
Ag: 1s22s22p63s23p64s23d104p65s14d10
Ответ:
1) Если это рубидий, то там 5 свободных 4d-орбиталей, электронная конфигурация 1s22s22p63s23p64s23d104p65s1.
2) Если это серебро, то там нет (0) свободных 4d-орбиталей, электронная конфигурация 1s22s22p63s23p64s23d104p65s14d10
В ответе на вопрос №186482 я уже описал квантовые числа. Не будем снова описывать их.
Согласно принципу Паули в атоме не может быть двух электронов с одинаковым набором квантовых чисел. Значит, набор n = 5, l = 0, ml= 0, ms = +1/2 соответствует только одному электрону. Значит, у этого элемента ровно 1 электрон на 5s (т.к. n = 5, l = 0) подуровне. Таких элементов 2: рубидий и серебро (т.к. у серебра есть провал с 5s на 4d-подуровень). Причём у рубидия все 4d-орбитали свободны (5 орбиталей) (они ещё не заполнялись, объяснение того, что орбиталей 5 - см. вопрос №186482), а у серебра все 4d-орбитали заняты (т.к. есть провал электрона).
Электронные формулы серебра и рубидия:
Rb: 1s22s22p63s23p64s23d104p65s1
Ag: 1s22s22p63s23p64s23d104p65s14d10
Ответ:
1) Если это рубидий, то там 5 свободных 4d-орбиталей, электронная конфигурация 1s22s22p63s23p64s23d104p65s1.
2) Если это серебро, то там нет (0) свободных 4d-орбиталей, электронная конфигурация 1s22s22p63s23p64s23d104p65s14d10
5
Большое спасибо!!!
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