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Задать вопрос экспертам

Консультация № 174695

30.11.2009, 00:31

0.00 руб.

0 1 1

Образование

1.Какие из карбонатов: ВеСО3 или ВаСО3 – можно получить по реакции взаимодействия соответствующих оксидов с СО2? Какая реакция идет наиболее энергично? Вывод сделайте, вычислив ∆Ԍ̊298 реакции.

Обсуждение

Неизвестный

30.11.2009, 01:23

общий

это ответ

Здравствуйте, Ёлкин Макс.
Запишем предполагаемые уравнения
BeO +CO₂ = BeCO₃
∆Ԍ̊298 (BeO) = -580.1кДж/моль
∆Ԍ̊298 (CO₂) = -394.4кДж/моль
∆Ԍ̊298 (BeCO₃) =-944,2 кДж/моль
∆Ԍ̊298(реакции) = ∆Ԍ̊298 (BeCO₃) - ∆Ԍ̊298 (CO₂) - ∆Ԍ̊298 (BeO) = -944,2 кДж/моль + 394.4кДж/моль + 580.1кДж/моль =
=30.3 кДж - реакция не идет - получить BеCO₃ таким образом нельзя

BaO +CO₂ = BaCO₃

∆Ԍ̊298 (BаO) = -520.3 кДж/моль
∆Ԍ̊298 (CO₂) = -394.4кДж/моль
∆Ԍ̊298 (BаCO₃) =-1134,4 кДж/моль
∆Ԍ̊298(реакции) = ∆Ԍ̊298 (BаCO₃) - ∆Ԍ̊298 (CO₂) - ∆Ԍ̊298 (BаO) = -1134,4 кДж/моль + 394.4кДж/моль + 520.3 кДж/моль =
=-219.7 кДж - реакция идет - таким образом можно получить BаCO₃

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