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Консультация № 152595
02.12.2008, 11:51
0.00 руб.
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1
1
1) Помогите пожалуйста написать уравнения диссоциацииэтих соединений в водных растворах:
1) 2NaNO2*Co(No2)3=Na3[Co(NO2)6]
2) 2KNO2*NH3*Co(NO2)6=K2[Co(NH3)(NO2)5]
3) CoCL3*3NH3*2H2O=[Co(NH3)3(H2O)2CL]CL2
2) Подскажите пожалуйста формулу акрилонитрила и схему полимеризации акрилонитрила.
Взаранеее благодарю и жду помощи!
1) 2NaNO2*Co(No2)3=Na3[Co(NO2)6]
2) 2KNO2*NH3*Co(NO2)6=K2[Co(NH3)(NO2)5]
3) CoCL3*3NH3*2H2O=[Co(NH3)3(H2O)2CL]CL2
2) Подскажите пожалуйста формулу акрилонитрила и схему полимеризации акрилонитрила.
Взаранеее благодарю и жду помощи!
Обсуждение
02.12.2008, 18:51
общий
это ответ
Здравствуйте, Панина О.А.!
При расстворении комплексных соединений в воде, комплексный ион (записываемый в квадратных скобках) диссоциирует в малой степени (степень диссоциации зависит от устойсивости комплекса, концентрации и некоторых других факторов), поэтому обычно пишут диссоциацию только внешней сферы (отделение ионов, не входящих в комплексный ион)
Na3[Co(NO2)6][$8594$]3Na++[Co(NO2)6]3-
K2[Co(NH3)(NO2)5][$8594$]2K++[Co(NH3)(NO2)5]2-
[Co(NH3)3(H2O)2Cl]Cl2[$8594$][Co(NH3)3(H2O)2Cl]2++2Cl-
Акрилонитрил CH2=CH-CN
Полимеризуется по двойной связи (-CH2-CH(CN)-)n
При расстворении комплексных соединений в воде, комплексный ион (записываемый в квадратных скобках) диссоциирует в малой степени (степень диссоциации зависит от устойсивости комплекса, концентрации и некоторых других факторов), поэтому обычно пишут диссоциацию только внешней сферы (отделение ионов, не входящих в комплексный ион)
Na3[Co(NO2)6][$8594$]3Na++[Co(NO2)6]3-
K2[Co(NH3)(NO2)5][$8594$]2K++[Co(NH3)(NO2)5]2-
[Co(NH3)3(H2O)2Cl]Cl2[$8594$][Co(NH3)3(H2O)2Cl]2++2Cl-
Акрилонитрил CH2=CH-CN
Полимеризуется по двойной связи (-CH2-CH(CN)-)n
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