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Консультация № 111262
27.11.2007, 18:47
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Здравствуйте! помогите составить уравнения электродных процессов и сумарное уравнение электролиза с инертными электродами раствора соли KI.
Обсуждение
27.11.2007, 18:53
общий
это ответ
<font color=red><b>!!!</b></font>
Здравствуйте, Козырев Сергей Андреевич!
Анод(+) 2I- -2e- = I2
Катод(-) 2H+ +2e- = H2
2KI + 2H2O = H2 + O2 + 2KOH <font color=red>!!! А куда йод подевался???</font><p><fieldset style=‘background-color:#EFEFEF; width:80%; border:red 1px solid; padding:10px;‘ class=fieldset><font color=red><i>Ошибка в уравнении</i>
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</font><font color=#777777 size=1><b>• Отредактировал: <a href=/info/user/8 target=_blank>Alexandre V. Tchamaev</a></b> (*Мастер-Эксперт)
<b>• Дата редактирования:</b> 27.11.2007, 21:16</font></fieldset>
Здравствуйте, Козырев Сергей Андреевич!
Анод(+) 2I- -2e- = I2
Катод(-) 2H+ +2e- = H2
2KI + 2H2O = H2 + O2 + 2KOH <font color=red>!!! А куда йод подевался???</font><p><fieldset style=‘background-color:#EFEFEF; width:80%; border:red 1px solid; padding:10px;‘ class=fieldset><font color=red><i>Ошибка в уравнении</i>
-----
</font><font color=#777777 size=1><b>• Отредактировал: <a href=/info/user/8 target=_blank>Alexandre V. Tchamaev</a></b> (*Мастер-Эксперт)
<b>• Дата редактирования:</b> 27.11.2007, 21:16</font></fieldset>
Неизвестный
27.11.2007, 20:49
общий
это ответ
Здравствуйте, Козырев Сергей Андреевич!
По-моему правильнее так:
Анод(+): 2I(-) - 2e = I2
Катод(-):2H2O + 2e = H2 + 2 OH(-)
На сколько мне известно по современным представлениям, восстанавливается именно вода, а не H(+), которые получаются по обратимой реакции 2H2O=H3O(+) + OH(-)
Суммарное уравнение реакции
2KI + 2H2O = H2 + I2 + 2KOH
По-моему правильнее так:
Анод(+): 2I(-) - 2e = I2
Катод(-):2H2O + 2e = H2 + 2 OH(-)
На сколько мне известно по современным представлениям, восстанавливается именно вода, а не H(+), которые получаются по обратимой реакции 2H2O=H3O(+) + OH(-)
Суммарное уравнение реакции
2KI + 2H2O = H2 + I2 + 2KOH
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