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Консультация № 198077
29.03.2020, 15:42
0.00 руб.
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Здравствуйте! Прошу помощи в следующем вопросе:
1. Напишите формулу соединения: нитрат диакватетраамминникеля (II)
2. Назовите соединение в соответствии с правилами номенклатуры:
[Co(NH3)5Cl]Cl2
3. Определите степень окисления комплексообразователя в соединении
[RhCl(NH3)5]Cl
4. Укажите координационное число центрального атома и координаци-
онную емкость лигандов в соединении (NH3)2[Ru(SO3)2(NH3)4]
Уровень В
1. Имеются два раствора – Na3[Ir(CN)4(SO4)] и Na2[Ir(CN)5(NO2)], мо-
ляльность которых равна 0,5 m. В каком случае понижение темпера-
туры замерзания раствора будет более заметным?
2. Как, используя спектрохимический ряд лигандов, объяснить измене-
ние окраски комплексов меди: [CuCl4]2- (зеленоватый), [Cu(H2O)]2+
(голубой), [Cu(NH3)4]2+ (интенсивно синий)?
3. Почему Pb медленно растворяется в разбавленной соляной кислоте, и
быстро – в концентрированной? Напишите уравнения соответствую-
щих реакций.
4. Какая кислота сильнее – HF или H[BF4]? Ответ обоснуйте.
Уровень С
1. Могут ли комплексы, образованные лигандами слабого поля, быть
диамагнитными? Ответ поясните.
2. Какие из перечисленных координационных соединений окрашены и
почему: [Ti(H2O)6]Cl3, [Cu(NH3)4]Cl2, Na[Ag(NO3)2]?
1. Напишите формулу соединения: нитрат диакватетраамминникеля (II)
2. Назовите соединение в соответствии с правилами номенклатуры:
[Co(NH3)5Cl]Cl2
3. Определите степень окисления комплексообразователя в соединении
[RhCl(NH3)5]Cl
4. Укажите координационное число центрального атома и координаци-
онную емкость лигандов в соединении (NH3)2[Ru(SO3)2(NH3)4]
Уровень В
1. Имеются два раствора – Na3[Ir(CN)4(SO4)] и Na2[Ir(CN)5(NO2)], мо-
ляльность которых равна 0,5 m. В каком случае понижение темпера-
туры замерзания раствора будет более заметным?
2. Как, используя спектрохимический ряд лигандов, объяснить измене-
ние окраски комплексов меди: [CuCl4]2- (зеленоватый), [Cu(H2O)]2+
(голубой), [Cu(NH3)4]2+ (интенсивно синий)?
3. Почему Pb медленно растворяется в разбавленной соляной кислоте, и
быстро – в концентрированной? Напишите уравнения соответствую-
щих реакций.
4. Какая кислота сильнее – HF или H[BF4]? Ответ обоснуйте.
Уровень С
1. Могут ли комплексы, образованные лигандами слабого поля, быть
диамагнитными? Ответ поясните.
2. Какие из перечисленных координационных соединений окрашены и
почему: [Ti(H2O)6]Cl3, [Cu(NH3)4]Cl2, Na[Ag(NO3)2]?
Обсуждение
В консультации пока нет ответов.
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