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Консультация № 191527
24.10.2017, 21:50
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Здравствуйте! У меня возникли сложности с таким вопросом:
при достаточно высоких температурах (порядка тысячи или нескольких тысяч градусов) наблюдаются отклонения от закона Менделеева-Клапейрона для газов из многоатомных молекул. Почему? ответ обоснуйте.
при достаточно высоких температурах (порядка тысячи или нескольких тысяч градусов) наблюдаются отклонения от закона Менделеева-Клапейрона для газов из многоатомных молекул. Почему? ответ обоснуйте.
Обсуждение
29.10.2017, 18:31
общий
это ответ
Здравствуйте, nkavatar!
При достаточно высоких температурах многоатомные молекулы газов начинают распадаться на атомы (а при очень высоких температурах - на ионы и электроны), поэтому используемое в законе Менделеева-Клапейрона значение молярной массы обычного газа становится неверным (следует использовать закон Менделеева-Клапейрона в форме для смеси идеальных газов).
При достаточно высоких температурах многоатомные молекулы газов начинают распадаться на атомы (а при очень высоких температурах - на ионы и электроны), поэтому используемое в законе Менделеева-Клапейрона значение молярной массы обычного газа становится неверным (следует использовать закон Менделеева-Клапейрона в форме для смеси идеальных газов).
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