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Консультация № 187950
02.12.2014, 21:50
100.51 руб.
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Здравствуйте! Прошу помощи в следующем вопросе:
1.Будет ли газофазная реакция 2SO2+O2=2SO3 протекать самопроизвольно в прямом направлении в изолированной системе при стандартных состояниях веществ и T=400K?
и если не составит труда подскажите правильно ли сделано 2 задание и почему будет так "[HCl]^4[О2]/[Сl2]²[H2О]² = Kc1² ∙ Kc2"
При T=const определены константы равновесия следующих процессов:
H2(г) + Cl2(г) ⇄ 2HCl(г), Kc1=24,3
2H2О(г) ⇄ 2H2(г) + O2(г) ,Kc2=0,84
Исходя из этих данных, рассчитайте Kc третьего процесса: 2H2O(г) + 2Cl2(г) ⇄ 4HCl(г) + O2(г),
а также укажите преобладающее направления протекания процесса при этой температуре.
Решение:
Kc1=[HCl]²/[H2][Сl2] = 24,3
Kc2=[H2]²[О2]/[H2О]² = 0,84
Kc3=[HCl]^4[О2]/[Сl2]²[H2О]² = Kc1² ∙ Kc2 = 24,3² ∙ 0,84 = 496,0 > > 1 - при этой температуре преобладает прямая реакция.
Приложение:
Заранее спасибо,надеюсь для вас не составит большого труда эти задания!!!)
1.Будет ли газофазная реакция 2SO2+O2=2SO3 протекать самопроизвольно в прямом направлении в изолированной системе при стандартных состояниях веществ и T=400K?
и если не составит труда подскажите правильно ли сделано 2 задание и почему будет так "[HCl]^4[О2]/[Сl2]²[H2О]² = Kc1² ∙ Kc2"
При T=const определены константы равновесия следующих процессов:
H2(г) + Cl2(г) ⇄ 2HCl(г), Kc1=24,3
2H2О(г) ⇄ 2H2(г) + O2(г) ,Kc2=0,84
Исходя из этих данных, рассчитайте Kc третьего процесса: 2H2O(г) + 2Cl2(г) ⇄ 4HCl(г) + O2(г),
а также укажите преобладающее направления протекания процесса при этой температуре.
Решение:
Kc1=[HCl]²/[H2][Сl2] = 24,3
Kc2=[H2]²[О2]/[H2О]² = 0,84
Kc3=[HCl]^4[О2]/[Сl2]²[H2О]² = Kc1² ∙ Kc2 = 24,3² ∙ 0,84 = 496,0 > > 1 - при этой температуре преобладает прямая реакция.
Приложение:
Заранее спасибо,надеюсь для вас не составит большого труда эти задания!!!)
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