[{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Мастер-Эксперт","roleIcon":"fa-user-ninja","socialMedia":[],"aboutText":"","aboutHTML":"","signatureText":"Facta loquuntur.","signatureHTML":"Facta loquuntur.","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":4.979,"absoluteRating":109933,"dynamicRating":1669.059,"dynamicRatingStars":10,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.3292153+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":11,"counters":{"daysAtPortal":6586,"questions":12,"questionsPosts":18346,"questionsAnswers":6664,"questionsPostsEvaluations":2832,"forumPosts":5699},"isRfproUserClass":true,"id":17387,"name":"Гордиенко Андрей Владимирович","email":"","role":10,"registDate":"1000-01-01T00:00:00","lastDate":"2024-05-29T19:25:04","photo":"users/17387/f4979bc95a484b9f43f75cfe66538acd.jpg","lastDateIndicatorClass":"red","lastDateIndicatorText":"давно","photoPreview200":"users/17387/200_f4979bc95a484b9f43f75cfe66538acd.jpg","photoPreview120":"users/17387/120_f4979bc95a484b9f43f75cfe66538acd.jpg","photoPreview100":"users/17387/100_f4979bc95a484b9f43f75cfe66538acd.jpg","photoPreview80":"users/17387/80_f4979bc95a484b9f43f75cfe66538acd.jpg","photoPreview40":"users/17387/40_f4979bc95a484b9f43f75cfe66538acd.jpg","isPhotoExists":true,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":true},{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Мастер-Эксперт","roleIcon":"fa-user-ninja","socialMedia":[],"aboutText":"Я пенсионер. Образование высш, радио-инж. Работал инж-электроником, ведущим средств телевидения, связи, слесарем и инженером КИП, грузчиком, программистом. На моём счету десятки рац-предложений, в тч с большим экономич эффектом.\nЯ люблю компьютеры, ремонтирую их друзьям и соседям. Пишу полезные программки в vbs-файлах, автоматизирующие настройку Win-систем, приложений и работу с ними.","aboutHTML":"Я пенсионер. Образование высш, радио-инж. Работал инж-электроником, ведущим средств телевидения, связи, слесарем и инженером КИП, грузчиком, программистом. На моём счету десятки рац-предложений, в тч с большим экономич эффектом.\u003Cbr\u003EЯ люблю компьютеры, ремонтирую их друзьям и соседям. Пишу полезные программки в vbs-файлах, автоматизирующие настройку Win-систем, приложений и работу с ними.","signatureText":"","signatureHTML":"","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":4.935,"absoluteRating":25767,"dynamicRating":458.574,"dynamicRatingStars":8,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.3296858+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":11,"counters":{"daysAtPortal":5618,"questions":25,"questionsPosts":7464,"questionsAnswers":1226,"questionsPostsEvaluations":789,"forumPosts":401},"isRfproUserClass":true,"id":259041,"name":"Алексеев Владимир Николаевич","email":"","role":10,"registDate":"1000-01-01T00:00:00","lastDate":"2024-05-28T14:33:20","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"red","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":true},{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Старший Модератор","roleIcon":"fa-user-tie","socialMedia":[],"aboutText":"634034, г.Томск, ул.Красноармейская 122, кв.173","aboutHTML":"634034, г.Томск, ул.Красноармейская 122, кв.173","signatureText":"","signatureHTML":"","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":4.985,"absoluteRating":21746,"dynamicRating":410.035,"dynamicRatingStars":8,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.3299445+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":13,"counters":{"daysAtPortal":5303,"questions":1,"questionsPosts":1973,"questionsAnswers":1283,"questionsPostsEvaluations":588,"forumPosts":91},"isRfproUserClass":true,"id":312929,"name":"Коцюрбенко Алексей Владимирович","email":"","role":12,"registDate":"1000-01-01T00:00:00","lastDate":"2023-11-05T17:20:40","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":true},{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Советник","roleIcon":"fa-user-ninja","socialMedia":[],"aboutText":"","aboutHTML":"","signatureText":"","signatureHTML":"","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":5,"absoluteRating":9460,"dynamicRating":381.988,"dynamicRatingStars":8,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.33022+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":10,"counters":{"daysAtPortal":2476,"questions":0,"questionsPosts":472,"questionsAnswers":398,"questionsPostsEvaluations":298,"forumPosts":1},"isRfproUserClass":true,"id":401284,"name":"Михаил Александров","email":"","role":9,"registDate":"1000-01-01T00:00:00","lastDate":"2024-05-25T12:02:55","photo":"users/401284/48171011af39b6bb3a74df8c0fcf97d0.jpg","lastDateIndicatorClass":"red","lastDateIndicatorText":"давно","photoPreview200":"users/401284/200_48171011af39b6bb3a74df8c0fcf97d0.jpg","photoPreview120":"users/401284/120_48171011af39b6bb3a74df8c0fcf97d0.jpg","photoPreview100":"users/401284/100_48171011af39b6bb3a74df8c0fcf97d0.jpg","photoPreview80":"users/401284/80_48171011af39b6bb3a74df8c0fcf97d0.jpg","photoPreview40":"users/401284/40_48171011af39b6bb3a74df8c0fcf97d0.jpg","isPhotoExists":true,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":true},{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Посетитель","roleIcon":"fa-user","socialMedia":[],"aboutText":"","aboutHTML":"","signatureText":"","signatureHTML":"","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":4.987,"absoluteRating":6052,"dynamicRating":219.675,"dynamicRatingStars":7,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.3304946+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":2,"counters":{"daysAtPortal":2755,"questions":0,"questionsPosts":527,"questionsAnswers":250,"questionsPostsEvaluations":155,"forumPosts":0},"isRfproUserClass":true,"id":400669,"name":"epimkin","email":"","role":1,"registDate":"1000-01-01T00:00:00","lastDate":"2024-05-30T00:53:01","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"green","lastDateIndicatorText":"в сети","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":false},{"isEmailConfirmed":true,"tel":"","ip":"0.0.0.0","ipLocation":{"ip":"","sDate":3,"postalCode":"","country":"","countryIsoCode":"","federalDistrict":"","region":"","regionType":"","city":"","cityType":"","geoLat":"","geoLon":"","locationString":""},"birthDate":"0001-01-01T00:00:00","age":0,"isBirthdayToday":false,"ban":{"id":0,"userId":0,"isBanned":false,"startDate":"0001-01-01T00:00:00","endDate":"0001-01-01T00:00:00","moder":{"id":0,"name":"Неизвестный","email":"нет адреса","role":0,"roleString":"Неподтвержден","roleIcon":"fa-user-clock","registDate":"0001-01-01T00:00:00","lastDate":"0001-01-01T00:00:00","photo":"images/unophoto.png?v=9.4.12","lastDateIndicatorClass":"gray","lastDateIndicatorText":"давно","photoPreview200":"images/unophoto.png?v=9.4.12","photoPreview120":"images/unophoto.png?v=9.4.12","photoPreview100":"images/unophoto.png?v=9.4.12","photoPreview80":"images/unophoto.png?v=9.4.12","photoPreview40":"images/unophoto.png?v=9.4.12","isPhotoExists":false,"isValid":false,"isLoggedIn":false,"isUnconfirmed":true,"isConfirmed":false,"isNewUser":false,"isExisted":false,"isExpert":false,"isRfproUserClass":false},"reasonHTML":"","timeToUnbanString":"-57 мин."},"isBanned":false,"roleString":"Посетитель","roleIcon":"fa-user","socialMedia":[],"aboutText":"","aboutHTML":"","signatureText":"[i]С уважением[/i]\n[i]shvetski[/i]","signatureHTML":"\u003Ci\u003EС уважением\u003C/i\u003E\u003Cbr\u003E\u003Ci\u003Eshvetski\u003C/i\u003E","country":{"id":0,"name":"","isFlagExists":false,"flagImage":"","isValid":false},"city":{"id":0,"name":"","countryId":0,"yandexCityId":0,"isValid":false},"averageEvaluation":4.963,"absoluteRating":11493,"dynamicRating":200.04,"dynamicRatingStars":7,"timezone":{"id":0,"baseUtcOffset":"00:00:00","displayName":"[не установлен]","linuxid":"notset/clean"},"currentDateTime":"2024-05-29T21:57:34.3307593+03:00","isValid":true,"isUnconfirmed":false,"isConfirmed":true,"settings":{"fixedHeader":true,"fixedFooter":true,"leftColumnMode":2,"darkTheme":false,"topPanelBtns":[{"id":103,"text":"Главная","title":"Главная (начальная) страница Портала","icon":"fa-solid fa-house-chimney","colorClass":"text-info-emphasis","controller":"Home","action":"Index","accessLevel":0,"isDropdown":false},{"id":100,"text":"Вход в систему","title":"Войти в систему с использованием своих регистрационных данных (адрес электронной почты и пароль)","icon":"fa-solid fa-arrow-right-to-bracket","colorClass":"text-info-emphasis","controller":"Login","action":"Index","accessLevel":0,"isDropdown":false},{"id":101,"text":"Регистрация","title":"Зарегистрироваться в системе и стать полноценным участником сообщества","icon":"fa-solid fa-user-plus","colorClass":"text-info-emphasis","controller":"Regist","action":"Index","accessLevel":0,"isDropdown":false},{"id":102,"text":"Сброс пароля","title":"Сбросить пароль свой учетной записи, если Вы его забыли","icon":"fa-solid fa-key","colorClass":"text-danger-emphasis","controller":"Login","action":"ResetPassword","accessLevel":0,"isDropdown":false}],"topPanelBtnsHideText":false},"isLevelUpAllowed":false,"nextRole":2,"counters":{"daysAtPortal":5745,"questions":35,"questionsPosts":1567,"questionsAnswers":588,"questionsPostsEvaluations":324,"forumPosts":44},"isRfproUserClass":true,"id":226425,"name":"Shvetski","email":"","role":1,"registDate":"1000-01-01T00:00:00","lastDate":"2024-05-29T20:46:51","photo":"users/226425/f345a2332af0cff5fba81b60c4e0d441.jpg","lastDateIndicatorClass":"red","lastDateIndicatorText":"давно","photoPreview200":"users/226425/200_f345a2332af0cff5fba81b60c4e0d441.jpg","photoPreview120":"users/226425/120_f345a2332af0cff5fba81b60c4e0d441.jpg","photoPreview100":"users/226425/100_f345a2332af0cff5fba81b60c4e0d441.jpg","photoPreview80":"users/226425/80_f345a2332af0cff5fba81b60c4e0d441.jpg","photoPreview40":"users/226425/40_f345a2332af0cff5fba81b60c4e0d441.jpg","isPhotoExists":true,"isLoggedIn":true,"isNewUser":false,"isExisted":true,"isExpert":false}]
Консультация № 186791
08.11.2012, 23:36
104.97 руб.
0
4
1
Здравствуйте, уважаемые эксперты! У меня возникли сложности с таким вопросом:
Имеется молекула FeCl2 хлорид железа.
Необходимо:
1. Составить структурную формулу
2. Показать образование химической связи в молекуле по методу валентных связей
3. Указать тип гибридизации центрального атома, геометрически изобразить форму молекулы
4. Определить полярность связей, их направленность, валентный угол
5. Определить полярность молекулы.
У меня получается железо d-элемент и какое-то нагромождение. В общем, помогите, пожалуйста.
Имеется молекула FeCl2 хлорид железа.
Необходимо:
1. Составить структурную формулу
2. Показать образование химической связи в молекуле по методу валентных связей
3. Указать тип гибридизации центрального атома, геометрически изобразить форму молекулы
4. Определить полярность связей, их направленность, валентный угол
5. Определить полярность молекулы.
У меня получается железо d-элемент и какое-то нагромождение. В общем, помогите, пожалуйста.
Обсуждение
Неизвестный
09.11.2012, 01:01
общий
это ответ
Здравствуйте, Елена!
1. структурная формула Cl- Fe-Cl
2. Fe Cl 2 имеет слоистую структуру, указана на рис 235 б) стр 533учебника Н. С. Ахметов. Общая и неорганическая химия. Москва " Высшая школа" 1988 год.
3 Форма гибридизации d 2 s p 3, форма молекулы Шесть орбиталей направлены от ядра атома Fe к вершинам восьмигранника октаэдра под углом 90 градусов одна относительно другой
4 Молекула полярна, электронная плотность смещена от иона железа к анионам хлора
1. структурная формула Cl- Fe-Cl
2. Fe Cl 2 имеет слоистую структуру, указана на рис 235 б) стр 533учебника Н. С. Ахметов. Общая и неорганическая химия. Москва " Высшая школа" 1988 год.
3 Форма гибридизации d 2 s p 3, форма молекулы Шесть орбиталей направлены от ядра атома Fe к вершинам восьмигранника октаэдра под углом 90 градусов одна относительно другой
4 Молекула полярна, электронная плотность смещена от иона железа к анионам хлора
Неизвестный
09.11.2012, 21:15
общий
Спасибо за ответ. Все понятно, кроме одного пункта: Как определяется d2sp3 гибридизация в данном случае?
Неизвестный
09.11.2012, 23:56
общий
Для железа (II) наиболее типично координационное число 6, что соответствует октаэдрическому расположению связей в комплексах и структурных единицах. Для образования 6 связей необходима гибридизация одной s, трёх p и двух d орбиталей Откуда и берётся d2sp3 гибридизация
Форма ответа
Отправка постов/ответов доступна только зарегистрированным и подтвержденным пользователям.
Если Вы уже зарегистрированы на Портале - войдите в систему, если Вы еще не регистрировались - пройдите простую процедуру регистрации.