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Консультация № 185300
26.01.2012, 09:16
60.32 руб.
0
5
1
Здравствуйте! Прошу помощи в следующем вопросе:
Написать выражение константы равновесия через равновесные концентрации веществ
H2(г) + S(тв) <=>H2S(г) ∆ H O <0<%2.1%> Указать направление смещения равновесия: а) при увеличении температуры, б) при увеличении давления, в) при уменьшении концентрации исходных веществ, для реакции. Ответ обосновать.
Написать выражение константы равновесия через равновесные концентрации веществ
H2(г) + S(тв) <=>H2S(г) ∆ H O <0<%2.1%> Указать направление смещения равновесия: а) при увеличении температуры, б) при увеличении давления, в) при уменьшении концентрации исходных веществ, для реакции. Ответ обосновать.
Обсуждение
26.01.2012, 22:56
общий
26.01.2012, 22:56
а) по знаку теплового эффекта (–Q) определяем, что прямая реакция экзотермическая, тогда обратная реакция будет эндотермической. Повышение температуры смещает равновесие в сторону эндотермической реакции, т. е. влево, в сторону обратной реакции;
б) В нашем случае слева в уравнении 1 моль газов, справа — тоже один моль. Изменение давления не окажет влияния.
в) понижение концентрации исходных веществ вызовет смещение равновесия в сторону увеличения концентрации этих веществ, т. е. влево.
б) В нашем случае слева в уравнении 1 моль газов, справа — тоже один моль. Изменение давления не окажет влияния.
в) понижение концентрации исходных веществ вызовет смещение равновесия в сторону увеличения концентрации этих веществ, т. е. влево.
28.01.2012, 18:19
общий
это ответ
Здравствуйте, Посетитель - 386361!
а) по знаку теплового эффекта (–Q) определяем, что прямая реакция экзотермическая, тогда обратная реакция будет эндотермической. Повышение температуры смещает равновесие в сторону эндотермической реакции, т. е. влево, в сторону обратной реакции;
б) В нашем случае слева в уравнении 1 моль газов, справа — тоже один моль. Изменение давления не окажет влияния.
в) понижение концентрации исходных веществ вызовет смещение равновесия в сторону увеличения концентрации этих веществ, т. е. влево.
а) по знаку теплового эффекта (–Q) определяем, что прямая реакция экзотермическая, тогда обратная реакция будет эндотермической. Повышение температуры смещает равновесие в сторону эндотермической реакции, т. е. влево, в сторону обратной реакции;
б) В нашем случае слева в уравнении 1 моль газов, справа — тоже один моль. Изменение давления не окажет влияния.
в) понижение концентрации исходных веществ вызовет смещение равновесия в сторону увеличения концентрации этих веществ, т. е. влево.
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