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Консультация № 185021
02.01.2012, 18:51
74.70 руб.
0
2
1
Уважаемые эксперты! Пожалуйста, ответьте на вопрос:
1) Ионные кристаллы и их электрофизические свойства.
2) Напишите электродные процессы в гальваническом элементе
(-) Zn/Zn(NO3)2(0.1M) // Pb(NO3)2(0.02M) / Pb(+)
и вычислите э.д.с. этого элемента
1) Ионные кристаллы и их электрофизические свойства.
2) Напишите электродные процессы в гальваническом элементе
(-) Zn/Zn(NO3)2(0.1M) // Pb(NO3)2(0.02M) / Pb(+)
и вычислите э.д.с. этого элемента
Обсуждение
Неизвестный
03.01.2012, 14:19
общий
Zn (0) - 2e = Zn (2+) окисление, на аноде
Pb (2+) +2e = Pb (0) восстановление, на катоде
Суммарная реакция Zn (0) + Pb (2+) = Zn (2+) + Pb (0),
ЭДС гальванического элемента ΔE = Eкатода - Eанода.
E = E0 + [RT/(z*F)]*ln[C]
E (Zn /Zn 2+) = -0,7628 + 0,059/2*In(0,1)= - 0,83 B
E (Pb/Pb2+) = -0,126 + 0,059/2*In(0,02) = - 0,241 B
ΔE = - 0,241 - (- 0,83) = 0,589 B
Pb (2+) +2e = Pb (0) восстановление, на катоде
Суммарная реакция Zn (0) + Pb (2+) = Zn (2+) + Pb (0),
ЭДС гальванического элемента ΔE = Eкатода - Eанода.
E = E0 + [RT/(z*F)]*ln[C]
E (Zn /Zn 2+) = -0,7628 + 0,059/2*In(0,1)= - 0,83 B
E (Pb/Pb2+) = -0,126 + 0,059/2*In(0,02) = - 0,241 B
ΔE = - 0,241 - (- 0,83) = 0,589 B
Форма ответа
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