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Консультация № 167585
17.05.2009, 23:52
0.00 руб.
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1
По заданным термохимическим уравнениям рассчитать стандартную энтальпию реакции образования СrF2 (к) из простых веществ:
а) 2Сr (к) + 3F2 (г)= 2СrF3 (к); [$916$] г Н[$186$] (298К) = -2224 кДж
б) 2СrF3 (к) + Сr(к) = 3СrF2 (к); [$916$] г Н[$186$] (298К) = -38 кДж...?????
а) 2Сr (к) + 3F2 (г)= 2СrF3 (к); [$916$] г Н[$186$] (298К) = -2224 кДж
б) 2СrF3 (к) + Сr(к) = 3СrF2 (к); [$916$] г Н[$186$] (298К) = -38 кДж...?????
Обсуждение
19.05.2009, 20:22
общий
это ответ
Здравствуйте, Maiskaya Yulya Petrovna!
Энтальпия первой реакции
[$916$]rH0(a)=2[$916$]fH0(CrF3)-2[$916$]fH0(Cr)-3[$916$]fH0(F2)=2[$916$]fH0(CrF3)
2[$916$]fH0(CrF3)=[$916$]rH0(a)/2=-1112 кДж/моль
Энтальпия второй реакции
[$916$]rH0(б)=3[$916$]fH0(CrF2)-2[$916$]fH0(CrF3)-[$916$]fH0(Cr)=3[$916$]fH0(CrF2)-2[$916$]fH0(CrF3)
[$916$]fH0(CrF2)=([$916$]rH0(б)+2[$916$]fH0(CrF3))/3=-754 кДж/моль
Энтальпия первой реакции
[$916$]rH0(a)=2[$916$]fH0(CrF3)-2[$916$]fH0(Cr)-3[$916$]fH0(F2)=2[$916$]fH0(CrF3)
2[$916$]fH0(CrF3)=[$916$]rH0(a)/2=-1112 кДж/моль
Энтальпия второй реакции
[$916$]rH0(б)=3[$916$]fH0(CrF2)-2[$916$]fH0(CrF3)-[$916$]fH0(Cr)=3[$916$]fH0(CrF2)-2[$916$]fH0(CrF3)
[$916$]fH0(CrF2)=([$916$]rH0(б)+2[$916$]fH0(CrF3))/3=-754 кДж/моль
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