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Консультация № 158552
23.01.2009, 18:09
0.00 руб.
0
3
1
При какой температуренаступит равновесие в системе:
CH4(г)+CO2(г)=2CO(г)+2h2(г)-247?4кДж
CH4(г)+CO2(г)=2CO(г)+2h2(г)-247?4кДж
Обсуждение
Неизвестный
24.01.2009, 16:24
общий
это ответ
Здравствуйте, Ildegurini!
В данном случае, скорее, имеется в виду температура, выше которой невозможно самопроизвольное протекание реакции или при которой константа равновесия реакции равна 1. Равновесие в реакции может наступить при ЛЮБОЙ температуре.
Приблизительное значение такой температуры считается путем деления энтальпии на энтропию. Энтальпию Вы привели, а энтропию посчитаю я.
S0 = 2S0(CO) + 2S0(H2) - S0(CH4) - S0(CO2) = 2 * 197.54 + 2*130.58 - 213.68 - 186.19 = 256.37 Дж/(моль*К).
T = 247400/256.37 = 965 K(или 6920 по Цельсию).
С уважением, Товарищ Бородин
В данном случае, скорее, имеется в виду температура, выше которой невозможно самопроизвольное протекание реакции или при которой константа равновесия реакции равна 1. Равновесие в реакции может наступить при ЛЮБОЙ температуре.
Приблизительное значение такой температуры считается путем деления энтальпии на энтропию. Энтальпию Вы привели, а энтропию посчитаю я.
S0 = 2S0(CO) + 2S0(H2) - S0(CH4) - S0(CO2) = 2 * 197.54 + 2*130.58 - 213.68 - 186.19 = 256.37 Дж/(моль*К).
T = 247400/256.37 = 965 K(или 6920 по Цельсию).
С уважением, Товарищ Бородин
Неизвестный
25.01.2009, 20:18
общий
Разница несущественна, это во-первых. Во-вторых, у того, кто считал и получил такой ответ, который дан у Вас, может немного отличаться значение изменения энтропии реакции. Я же не знаю, какие у него, у этого кого-то, были исходные значения. Вот и надо воспользоваться теми справочными материалами, которыми он пользовался, и посчитать.
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