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Консультация № 138395
28.05.2008, 23:55
0.00 руб.
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Уважаемые эксперты, помогите пожалуйста ответить на вопрос по коррозии металлов: Что является окислителем при коррозии металлов в щелочной среде? Помогите составить уравнения реакций, протекающих при коррозии цинка в щелочной среде.
Спасибо.
Спасибо.
Обсуждение
29.05.2008, 09:39
общий
это ответ
Здравствуйте, Dasha Kotova!
Окислителем в нейтральной и щелочной среде является вода. В случае амфотерности (Al, Zn) в щелочной среде поисходит образование комплекса
K(-) 2H<sub>2</sub>O+2e<sup>-</sup>=H<sub>2</sub>+2OH<sup>-</sup>
A (+) Zn+4OH<sup>-</sup>-2e<sup>-</sup>=[Zn(OH)<sub>4</sub>]<sup>2-</sup>
Zn+2OH<sup>-</sup>+2H<sub>2</sub>O=[Zn(OH)<sub>4</sub>]<sup>2-</sup>+H<sub>2</sub>
Окислителем в нейтральной и щелочной среде является вода. В случае амфотерности (Al, Zn) в щелочной среде поисходит образование комплекса
K(-) 2H<sub>2</sub>O+2e<sup>-</sup>=H<sub>2</sub>+2OH<sup>-</sup>
A (+) Zn+4OH<sup>-</sup>-2e<sup>-</sup>=[Zn(OH)<sub>4</sub>]<sup>2-</sup>
Zn+2OH<sup>-</sup>+2H<sub>2</sub>O=[Zn(OH)<sub>4</sub>]<sup>2-</sup>+H<sub>2</sub>
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